• Go to Image >Adjustments > Photo Filter.
• Apply Warming Filter.

• Create a new layer.
• Place it above hair layer.
• Fill hair area with black color using soft brush.
• Go to Filter > Texture > Grain.(100; 100; Soft).

• Apply Screen Blending Mode.
• Duplicate this layer. (Opacity 60-80%).

• Add vector mask to face layer.
• Erase sights of hair on several flowers areas.

• Create a new layer.
• Click "D' to default colors.
• Go to Filter > Render > Clouds.
• Go to Filter > Stylize > Glowing Edges (14; 15;17).
• Erase face area using large soft brush.
• Apply Screen Blending Mode and Opacity 74%.

• Create round selection.
• Go to Select Refine Edge, apply the following settings:

• Select > Inverse selection.
• Fill selection with white color.

And here is the result! Click for larger view.